Question
How can Rpi talk to Arduino in RF?
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Answer
For poor IoT hobbyists like me, I would suggest to start with:
(1) BLE (2.4GHz),
(2) NFC (13.56MHz), and
(3) 5G (452.5 ~ 467.5MHz, 700MHz~ 2.2GHz)
Above three are wild choices.
For newbies, I would eliminate
(1) BLE, because RPi4B buster BLE still have teething problems,
(2) NFC, because it is only for short range (< 10cm),
(3) 5G (LTE-M), because it might also have teething problems, when finally coming to town, hopefully in 2020April.
So I think
2.4GHz modules such as nRF24L01+ seems to be the optimum choice for newbies.

And for hobbyists, I would recommend the popular, but still cheap, US$1 module nRF24L01+. You can find loads of Arduino tutorials on this cheap module. There is also a Rpi to Arduino tutorial (Ref 2, 3).
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References
(1) Connect Your MCU - Øivind Loe, Senior Product Manager – MCU and Sensors, Silicon Labs, 2020feb
(2) Rpi SPI nRF24L01+ 2.4GHz Transceiver Module Send Message to Arduino Problem (Q&A)
(3) Rpi SPI nRF24L01+ 2.4GHz Transceiver Module Send Message to Arduino Problem (Chat Record)
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Appendices
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Figures
Fig 1

Fig 2

Fig 3

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Fig 4

Fig 5

End of Answer
certain RF modulation
... that meansspecific RF modulation
..... why did you not say which RF modulation you are talking about?